I like Kodi the best. But I am upmixing to 7.1, and to me it has the best sounding upmixer. It has a lot of other problems, but Kodi gets that much right.
Upmixer aside, quality is not much of an issue in front of the DAC. When you are using USB or HDMI, the digital audio will be bit perfect.
I do run my audio through a program called FXSound that I think makes it sound better. But it is modifying the digital audio, not making it more accurate, it's already bit perfect after all.