@skyy92677 said:
I too just completed a new home build with a dedicated audio room.
New house.
I had a master electrician here 3 times now to no avail. We installed a second earth ground rod on the panel which he claimed should fix it, it did nothing.
Was it your idea to add an additional ground rod to the two that are already there? Adding the additional ground rod wouldn’t have solved your problem. It may have given you a lower soil resistance for the grounding electrode system for the Earth connection of the electrical service. The main purpose for the connection to Earth is for lightning protection.
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I also have a Siemens whole house surge protector but have the breaker turned off for it as when it’s on the the hum doubles in volume.
It’s so bad that when I turn the whole house surge on you can hear the toaster buzz!
What did the Master Electrician say about the two quotes above problem?
I can not visualize any way the Siemens Type 2 SPD could cause such an event as you have described. The electrical panel should be full of 120V single pole 15 and 20 amp AFCI, (Arc Fault Circuit Interrupter), branch circuit outlet breakers. An AFCI breaker has a built-in micro processor that senses a series or parallel arcing fault event. I would think the Siemens SPD would drive the electronics in the AFCI breakers nuts, causing them to trip open on a false arc fault event.
FWIW, my understanding, for one of the reasons for NEC requiring surge protection at the main electrical equipment panel, was to help protect the AFCI breaker’s internal electronics from high voltage transient surges. If you have the breaker turned off the electronics in the AFCI breakers are not protected.
You said the house was just recently built. I don’t know about your State but my State requires the builder to stand behind any defects, I believe for one year. I suggest you call the builder and tell him you have a serious electrical problem. Ask him if he will have the Electrical Contractor send out a troubleshooting Service Electrician to look at and fix the problem.
Before addressing the hum/buzzing issues with your audio system zero in on the Siemens SPD at the electrical panel and the toaster buzzing, (when being used), when the SPD breaker is closed, (connecting the SPD to the electrical bus) of the panel. Then you can tell the electrician the problem with your audio system.
Not that it should matter, I assume the toaster uses a 2 wire cord and plug. No safety equipment ground is used.
Just curious, does any of the Links provided below sound like the buzzing sound you are hearing?
CAUTION, turn down the volume before listening to the examples. Especially the last example.
This is a standard 60Hz ground loop hum.
1) 60Hz hum
2) 60Hz audio buzz example
Or maybe this.
3) 120Hz
Or maybe this.
4) 120Hz buzz (Make sure volume is turned down first)
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120Hz could indicate a high level of harmonic distortion on the AC mains. You said you tuned off all the breakers in the panel at one point. Including the Siemens SPD breaker. Only having one breaker on that fed your audio system. Doing so didn’t make any difference. Hum was still present. But not as loud when the Siemens SPD breaker was turned on. I still am shaking my head on that one. Makes no sense what so ever... That’s the first thing the Service Electrician will want you to show him. I would want to see and hear that first hand using the toaster. 
How about any neighbors that are fed from the same Utility Power Transformer as your house. Any solar panels on the roof(s)?
Are any of the neighbors experiencing electrical problems like you are having?
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