85% is clipping territory for sure. Yes, you will need to replace the
tweeters. Clipping happens when a amp runs out of power and starts
distorting . This distortion cooks the tweeters. If you need to play at the
volumes that clipped the tweeter, you should get a amp with more power to
drive the speakers with out running out of power.
Hope this helps. I've clipped tweeters before I learned how not to do it.