I have a couple Japanese repressings of the Decca The Planets, performed by Mehta and the LA Phil in 1970. The Decca version was one of HP's "Super Disks," and I've used the Japanese audiophile pressings for many years for judging components. This work includes high-pitched massed violins, loud brass, organ pedals, big soundstage and wide dynamics, and I enjoy listening to it; as a performance it's my favorite version of The Planets.
Another classical recording I've often used is the ASMIF 1st Brandenburg Concerto on Philips. It's revealing how different components differentiate the unison playing of the bassoon and bass and how they handle the dissonant, held notes of the French horns.
I have a Connoisseur Society LP of Ivan Moravec playing Debussy and Ravel piano pieces that I also use--it's been praised by one of the Stereophile writers as a particularly good piano recording (I agree), and acoustic piano is an excellent instrument for evaluating audio gear.
I also use US or UK pressings of DSOTM (although I prefer my MFSL Meddle) and my first pressing of Aja.
I might also use my Classic Records reissue of the first Led Zeppelin LP or the MFSL of the 2nd, or my MCA Super Vinyl of Who's Next.