In this setup my Node2 does the full MQA unfolding before sending it to the DAC (via digital coax).
Actually, no. You only get the full unfold if you send output to the analog outs of the Node 2.
https://support1.bluesound.com/hc/en-us/community/posts/360037876633-MQA-Confusion
I have yet to see a technical reason as to why the streamer does or doesn't matter, but my experience was that an external DAC did improve sound quality (in my case an Auralic Vega), but that replacing the Node 2 with a higher end streamer/DAC (for me it was the TEAC NT-505) resulted in a greater improvement in sound quality, a less "digital" sound, and a larger more "holographic" soundstage. As others have said, the app you use to control your streaming is also important.