I’m glad you are adding your voice to those who know from experience that not only is a PC more than adequate as a streamer, it is often superior. Also (and I didn’t even think of that before) it is true that:
Cool thing with custom builds is you get to hear what individual components add to the mix, everything matters.
Very true! I must however respectfully point out that there is no such thing as a "Windows motherboard". Now, Windows has been the dominant OS for 40 years, and it follows that motherboard design certainly accommodates Windows, but motherboards are by definition agnostic.
Although Taiko successfully runs Windows in their Extreme, Linux is probably better suited to a DIY build due to its almost infinite customizability. Right out the box, Windows does not want you to customize it and it will resist.
One last word, "Enterprise" motherboards (that is, server boards) are preferred because of their relative lack of features and absence of related componentry, thereby eliminating potential noise sources; a few of those boards also natively support SFP (the main fiber Ethernet standard), which is desirable as it provides 100% galvanic isolation between the PC and the next component in the chain, thereby ensuring that any noise that happens in the computer, stays in the computer.