It's not really about loudness, it just feels more powerful at the same volume.
@inna, Mapman has it right. The reason the tube amps sound like they have more power is because of how they make distortion when approaching full power. Unless its an SET, with most tube amps the higher ordered harmonics start showing up in greater amounts near overload. This interacts with the ear which imparts the impression that its louder- more powerful. This has given rise to the false notion that tube power is more powerful than solid state.
But like @mapman pointed out, if you have a sound pressure level meter, you'll find that its not louder- and in fact might be quieter.
I mentioned the caveat of SETs- they take this to an extreme by producing those higher ordered harmonics at a much lower power level- perhaps only 20-25% of full power, which is why many people talk about their 'dynamics' (since power is used the most on transients). But what they are really talking about and also in this case is distortion and how it interacts with the human ear (the ear uses higher ordered harmonics to gauge sound pressure).
Tubes make it an enjoyable experience since there's plenty of second order harmonics to go around too.