Why do people buy preamps if they can directly connect amp to stereo source/phone/PC/tv?

For those that like tube coloration (or distortion. for you detractors), messing around with tubes is a joy.  For those that prefer more sonic honesty, you will need to spend considerably more for tubes and may well find sonic bliss with a less expensive, but well specified solid state unit.

I feel that the tubes are more honest, generally speaking; solid state has a coloration of brightness and hardness.

^^ In addition to that, a good preamp provides control over the interconnects and in so doing, allows the system to be more neutral. This function seems to be the least understood, but seems to be pretty important, otherwise the system only sounds as good as your cables.
The funny thing? People often talk about a 'straight wire with gain' but the truth is that straight wire can introduce colorations unless properly controlled! That is because wires have a dielectric, can pick up noise, can have stray capacitance issues and so on. There is a bit of mythology there...