I agree with the TV placement. The diffusion from the stone wall could be very beneficial but you may need to compensate for it if you end up with too much mid/treble energy in the room. To compensate for this you'd add more panels elsewhere. Regardless of the fireplace another thing to keep in mind is your bass modes. Having a waterfall or flame graph of the room decay is going to help guide your need for bass traps.
Don't forget your ceiling when treating the room.
Don't forget your ceiling when treating the room.