Enzymes are biological catalysts that are generally some kind of protein. There is the “lock & key” analogy associated with enzymes and cleaning. The particular enzyme must be the right key to unlock (dissolving) the particular soil. There are four (4) basic enzymes used and how each works can be contaminant, time, concentration and surface dependent, and they have to be rinsed.
For further details read the book PACVR 3rd Ed Section VIII.9. Otherwise, if you read Chapter XII you may see some cleaning agent options for vacuum RCM.