Hey there,
Wold you consider wall or ceiling mounting in front of the fireplace?
Next to the couch IS the best place for the sub. I don't think adding a second sub is going to be worth the effort to get right. I DO think that you are going to need EQ or room correction to get any of this right. You need EQ to balance the main speakers and high pass filter them. This will reduce the problems you are going to have with one being very close to a wall and the other not.
To integrate that single sub you'll need a good DSP based EQ to clip strong room modes and blend them in with the mains. Otherwise you'll probably be caught between muddy/boomy bass and no bass. How exactly you do this depends on the rest of your system. Roon can help you, as can devices from miniDSP, or you can get a receiver with it built in.
If you were up for room treatment, I'd suggest it on the right and behind the couch, and big bass traps on the two corners on the left. I assume due to other circumstances none of this is an option. :)