Interestingly, a few hours of warm up applies to solid state gear as well. In fact the manufacturer of my solid state preamp recommends at least two days of warm up before listening, then leave it on continuously, turn it off and you will start over! I believe that these warm up periods involve the electrons finding their shortest signal path as well as transistors or tubes reaching their optimum temperature.
Seems like the best "upgrade" for tube amps....
...is to leave the amps on for a few hours before playing. I've noticed recently that when I turn on my Joule amps and let them run for hours, it makes a huge difference in the dynamics and high end sweetness. It gets hot in our house, but it's worth it. Is there a technical reason for this?