Diffusers placed behind front firing speakers will result in very minimal improvements at best. Back wall and rear of sidewalls placements would result in better results. Key for diffusion is to place at points of reflections. Behind front firing speakers is one of the last place you will experience reflection. If your room is overly deadened, place diffusers on first reflection points. If lively enough as is, place them on back wall. See my system with multiple pics showing my acoustic setup. The key to room acoustics starts with what your goals are, liveling up your room with diffusers, or deadening it with absorbers. Only you know. The key is usually a little of both until you get it right.