Derek, just a question for clarity: did you intend to connect some of your speakers directly to the AVR 230 and some of your *other* speakers directly to your AVR 335?
If so, then each set of speakers will be separately driven by each receiver and you will *possibly* give more power to your speakers due to the increased power supply capacity each receiver then will have available to drive the fewer number of speakers hooked to it. (Note: this possibility is very equipment specific and depends on how the power supply and internal amplifiers are configured to support all of the channels. One of the big issues in any amplification equipment is the capacity and robustness of the power supply. This can be far more critical to the real world performance of the amplifier/receiver than the wattage rating.)
The challenge in this approach is that you would now have two separate control centers (volume controls, etc) to manage to keep the audio signal synced among all of your speakers. Still, it could be an interesting experiment with no real cost other than some time.
If you simply cascade the signal from the AVR 230 into the AVR 335, then, as Rich says, you're simply substituting one internal linestage for the other, not gaining any additional power.
.