I'm not sure what you mean by passive biamping. You won't double your power by using 2 channels for each speaker; each channel is still 100 watts. You are, however, in a position to increase you sound quality if you do a vertical biamp. You can do that by running the signal from your preamp to the inputs on a pair of channels that share the same power supply. Then take the left and right signal from those 2 channels and plug them both in to one of your speakers. One speaker cable goes to the highs and the other to the lows on you binding posts. Do the exact same thing for the other channel.
Passive biamping question
If I have a six channel amplifier with one power supply per two channels and say each channel puts out say 100 watts, if I biamp with two channels per speaker for the three front channels of a HT system will this be basically like having 200 watts per channel and will the frequency balance of the speakers remain essentially the same? Thanks.