Stuart:
I've checked your room pics. I second Newbee on trying toe in the speakers maybe not as radical but some you'll have to play with them as usual. Your room dimensions are close to mine and I ran into problems when I opened the speakers apart too much. Your idea of tweeter position inside or outside seems interesting to explore. I have noticed your bass trap type acc treatments. Do you have something for side wall reflections your "like corner" pic doesn't show clearly but there seems to be some furniture very close to the speaker, correct?
Do you have any acc treatment behind your seating position? WHat's your seat distance to back wall?
If cable length allows would really suggest you try to move back the rack and TV 2 ft behind speaker plane ....
Maybe you have tried before some of this ideas but would like to hear your comments
Regards
Luis