This is probably the best HiFi store in London:
https://www.kjwestone.co.uk
Harrods in Knightsbridge is also worth a visit, not necessarily high end HiFi, but interesting. Also, probably the best department store in the world IMHO. Harrods also has a great selection of restaurants with a food hall second to none. I tell all my American friends, Harrods makes Neiman Marcus look like a Walmart!