That is a good question.
Listening skills are developed over decades. Values in sound quality change over time with your listening skills (learning about both good and bad attributes) … which in turn influence what you value in terms of sound quality. Also, when you hear a system it takes a lot of experience to figure out what is doing what to the sound… like is that the amp / preamp that is cold or the speakers? Etc.
So, I would say the less experience you have with high end audio the more time you need to appraise gear. Of course, if you have only had mid-fi stuff and you bring home a high end piece it can only take a second to get it. So, lots of caveats.
I remember a piece I brought home early on that I thought sounded great until I heard the “grain” in the treble. Wow, that was bad… I can hear grain in a couple seconds now.