I've been dealing with this exact same issue since I've been in my present room. In my case it is an asymetric room giving greater boundary reinforcement to one channel. When you have this issue with a room, balance controls may not entirely solve the problem as some frequencies may be reinforced more than others.
You can measure for any imbalance in your equipment by measuring voltage at speakers out on your amplifier. Play steady state tones at various frequencies and measure with the 2volt setting on DMM.
You can measure for any imbalance in your equipment by measuring voltage at speakers out on your amplifier. Play steady state tones at various frequencies and measure with the 2volt setting on DMM.