I founds some on-line pics of your int amp and your proposed sub:
http://vintageaudio.dualpixel.com/photos/Integrated%20Amplifiers/Yamaha%20CA-2010%2003.jpg
http://www.hometheaterhifi.com/press/wp-content/uploads/2013/09/PSB8.jpg
From the pics, it looks like what you can do is set the coupler switch on the back of the Yamaha to "off", then you would need a set of "Y" RCA adapters to plug to the L/R preouts on the 2010 to the main inputs to 'recouple' the pre and amp sections, and then run RCA cables to PSB line level inputs.
http://vintageaudio.dualpixel.com/photos/Integrated%20Amplifiers/Yamaha%20CA-2010%2003.jpg
http://www.hometheaterhifi.com/press/wp-content/uploads/2013/09/PSB8.jpg
From the pics, it looks like what you can do is set the coupler switch on the back of the Yamaha to "off", then you would need a set of "Y" RCA adapters to plug to the L/R preouts on the 2010 to the main inputs to 'recouple' the pre and amp sections, and then run RCA cables to PSB line level inputs.