I don't know if I can answer precisely enough to be of any help but from my experience the ProAcs had a more well-defined placement of the instruments and voices so that the sound stage seemed more realistic and deeper, more three-dimensional.
The ProAcs are legendary for their mid-range and that has been true for me for both pair of ProAcs I've owned. That's especially noticeable with vocals. The Thiel's are certainly more of a full-range speaker and more true to the sonic texture of larger-scale music.
They're both very good speaker brands, though very different from each other. Ultimately, the reason I chose the ProAcs over the Thiels is that I was able to more easily forget about the speakers and just hear the music but I did sometimes miss the excitement of the Thiels.
The ProAcs are legendary for their mid-range and that has been true for me for both pair of ProAcs I've owned. That's especially noticeable with vocals. The Thiel's are certainly more of a full-range speaker and more true to the sonic texture of larger-scale music.
They're both very good speaker brands, though very different from each other. Ultimately, the reason I chose the ProAcs over the Thiels is that I was able to more easily forget about the speakers and just hear the music but I did sometimes miss the excitement of the Thiels.