"Btstrg" and "Satch" - Another great choice and Eddie is another of my huge favorites! "Pje" is getting way too serious about this! It's supposed to be fun. We are not analyzing the notes, but how you were just blown away by a certain guitar solo. It's all a matter of personal fav's and nobody is wrong. I just like to have others help me explore music I haven't experienced and the electric guitar solos are the most emotionally exciting for me.
Best guitar explosion of all time
My vote is for Jimi's Voodoo Chile - a Slight Return! No one has come close to his majic on that recording. I am a big Jeff Beck, Jimmy Page, Eric Clapton fan and everything they have done falls short. Not for emotional involvement, or technical virtuousity, but for the finality of the perfect guitar moment. Jimi hit it on the mark - and then some!