Strings produce a bunch of different frequencies that make them sound like a string. The technique used to vibrate the string changes the frequency profile, if you will, of the sound. A hard pick produces different frequencies than fingers, etc.
One good example song is "Snuggle Up" by Brian Bromberg. If your low end is clean and clear enough, there’s a lot of very low frequency pitches mixed with textures on top from fingerstyle playing with muted plucks. A pure synthetically produced sine wave at the same fundamental frequencies would just sound like pure tones, without the overlaid textures.