I had the Motion 40's (same tweeter) and then the upgraded AMT tweeter (bigger) in the ML 35XTi, which was a good bit better that I could not go back to the Motion 40's.
The tweeter in the newest ML, the B100 (which is way more expensive) is the "gen 2" tweeter (35Xti being the first generation). The B100 has the "waveguide" built into the cabinet, but otherwise it is the same size. I could not hear a difference between the 35Xti (that I still have) and B100 I heard at Best Buy.
I only bi-wired my 35Xti's, using Audioquest Type 4 or 5. If the manufacturer goes to the expense of adding a second set of speaker terminals, I see that as a sign that it does increase performance.
It certainly is not your DAC. I have an Yggy and it is not bright. Would suggest leaving it on all the time though. If you ever feel the case of the Yggy and its slightly warm, it will sound best.
Someone mentioned using a better pair of tubes that came with your Preamp. That will help a lot. Probably should have done that before switching out your speakers as it makes a difference with all speakers. The JJ tubes that came with my Rogue RP-1 were far inferior to the NOS Mullards ($120 a pair) that I replaced them with. Most noticeably in the upper frequencies.
Your room, not treated, certainly has something to do with your perceived brightness. In fact, that may be where you could make the most difference using the least amount of money.
I love AMT tweeters. But I generally listen to soft dome with a pair of Wharfedale Linton Heritage Speakers. Since AMT is relatively new to market (90's when the patent expired allowing the technology to be utilized by many- and blossomed in the 2000's) there is (as someone stated) a wide margin between low dollar AMT speakers and high dollar AMT speakers. Hence, if I had my druthers, I would have a pair of Wharfedale Elysian's (5K and up) which have a super AMT tweeter instead of the Heritage with soft dome I listen to now.
IMHO, the ML 35XTi with its AMT Tweeter provides better highs than the soft dome on the Linton's- at a far lesser price especially if used - but with the Lintons everything else is better mid-bass, bass, cohesiveness..etc. But AMT tweeters - good ones - really are a treat, especially with expressive tubes in the Preamp outputs.