Hi, n80,
If I understand your question correctly, you'll need a separate Node for each listening environment. That is, one for your hi-fi system and one for wherever else you have a system. For example, I have two Nodes, one in the basement stereo room and one in the living room. I can access either Node to play music using the BluOS controller from our laptop or notebook but I had to have a Node upstairs and a Node downstairs to play different music in each room. You can sync the Nodes to play the same music in each room as well.
Regards,
Tom