I like using pure unplated copper spades. The Pangea Audio Xtreme Spades are made from Tellurium Copper (C14500?) so conductivity should be about 90-93% IACS (International Annealed Copper Standard), which is as good as it gets for a copper alloy. I doubt you would ever hear a difference between those and pure copper.
The conductivity differential becomes more pronounced with materials like C36000 Brass, C54400 Phosphor Bronze, C17500 Beryllium Copper, which have low conductivities in the range of about 19% to 40% IACS. My old Classe' Twenty Five amplifier had brass binding posts. Most banana plugs are made from a copper alloy, which is why the KLE bananas that are made from silver plated pure copper are so well respected.