Quite a number of posts here are not answering OP's question, which I must say I find a strange one.
How to make a small room sound bigger.
Why? My objective would be to improve the SQ. As some have posted, making the room sound better will not necessarily do that. In a concrete shell the sound will sound like it's in a big room because of the multiple reflections with extended overhand period. Agreed it certainly won't sound good, but it will sound big.
Room treatments such as those sensibly advocated above will certainly improve the SQ but they won't make the room sound bigger.
OP, perhaps you will explain your objective more fully?