I have noticed that when I am barefoot and gently rub my finger over the metal surfaces of the laptop that I feel a slight fuzziness as if there is stray voltage going through me. It is not a shock per se and the sensation goes away when the charger is unplugged.
I assume the floor is bare concrete or maybe some type of conductive tile. Concrete is conductive. Especially when poured on grade, earth.
I believe what you are experiencing is a very low level electrical shock. Your body may be sensitive to low levels of electrical current passing through it.
Just a guess a difference of potential exists between the laptop and the concrete floor. I would suggest you wear slippers on your feet or some other type of insulator