Passive biamping with a 100x2 amp is not like sending 200 watts to your speaker - it's merely a very common misconception.
The usable power going to your speakers is really still only 100wpc since that is the maximum power dictated by the voltage swing available from the amplifier.
Now, OTOH, if these amps can be bridged you would have a meaningful increase in output voltage swing as bridging operates the channels inverted from each other. When the channels operate inverted you get up to twice the voltage swing and twice the voltage swing means 4x power - provided the amp's power supply can keep up, that is.
The usable power going to your speakers is really still only 100wpc since that is the maximum power dictated by the voltage swing available from the amplifier.
Now, OTOH, if these amps can be bridged you would have a meaningful increase in output voltage swing as bridging operates the channels inverted from each other. When the channels operate inverted you get up to twice the voltage swing and twice the voltage swing means 4x power - provided the amp's power supply can keep up, that is.