Matching two amps is trivial.
There is no matching to be done, other than level setting. Just about every electronic crossover has level adjustments for every band.
Regardless of the "gain" of an amp, when you increase the input by 3dB, the output goes up 3dB. So, all you have to do is to put a level into amp 2 that when compared at the speaker output using pink noise gives the *same* level on your SPL meter as does amp 1. Of course, your ear will be the final arbiter of the precisely perfect relative levels.
If your electronic xover does not have level controls, and your amp does not either, you can either build a fixed pad into a small box - after measuring the dB difference with no pad. Or you can buy an after market in-line adjustable attenuator box to put in line with the amp that is "too loud" to reduce its level. Alternately, you can drill some holes into your amp and put a small rotary switch with MF resistors and make your own attenuator built in,or just put a decent pot there... I do that all the time on Phase Linear 400s that are used as subwoofer amps from time to time (on the front panel of the PL400, to match the PL700).
All done.
_-_-bear